Emerging contaminants in the northwest area of the Tai Lake Basin, China: Spatial autocorrelation analysis for source apportionment and wastewater-based epidemiological analysis.

In the present study, 60 emerging contaminants (ECs) were detected from 88 target compounds in the district of Wujin, which is the northwest area of Tai Lake Basin, China. Among them, CF (caffeine), a type of PhAC (pharmaceutically active compound), was detected as the pollutant with the highest concentration. It was observed that the removal efficiencies of PFASs (per-/polyfluoroalkyl substances) in wastewater treatment plants were lower than those of pesticides; further, those of pesticides were lower than those of PhACs. Based on the spatial agglomeration estimated by the spatial autocorrelation model, the probable sources of 28 contaminants were identified. This model provided a new perspective that would help to clarify the location of sources with high accuracy. The point sources of 6 PFASs and 14 PhACs were successfully found; in contrast, the main source of pesticides was identified as an agricultural nonpoint source. Finally, the potential risks of the ECs were also assessed in this study, including their aquatic ecological risks and human exposure risks. It was concluded that pesticides generally had the highest ecological risk, followed by PFASs and PhACs. To evaluate the population risk of pesticides, the wastewater-based epidemiological model was extended to back-calculate the per capita pesticide consumption, which was 0.22 g d-1 (103capita)-1.

Pollution characterization of pharmaceutically active compounds (PhACs) in the northwest of Tai Lake Basin, China: Occurrence, temporal changes, riverine flux and risk assessment.

PhACs have attracted great attentions of researchers because of their potential ecological and healthy risks. However, their long-term pollution tendency study is very scarce. In this study, 32 target PhACs from surface water, wastewater treatment plants, fishponds and livestock farms were investigated in Wujin, a city located in the northeast of Tai Lake, using grab sampling. The occurrence, spatiotemporal distribution characteristics, potential sources, riverine flux and risk assessment were systematically analyzed. It was found that non-antibiotics were the mainly PhACs category in Wujin and CF, SMX were the predominant non-antibiotics and antibiotics, respectively. Besides, the average concentrations of total PhACs were 586.6 ng L-1 and 273.2 ng L-1 in 2018 and 2019, respectively. This improvement could be mainly attributed to the closure of fishponds and livestock farms. Moreover, CF/CBZ ratios which was considered as an indicator to trace untreated wastewater decrease significantly in 2019, and this was also a main reason for the improvement. Riverine flux could be calculated through arranging control sampling sites in the boundary and the net riverine inflow flux of PhACs in Wujin was 264.3 kg/a. Finally, CF, SMX, EM were evaluated as the high risk contaminants based on a comprehensive risk assessment method.

Occurrence, spatiotemporal distribution, seasonal and annual variation, and source apportionment of poly- and perfluoroalkyl substances (PFASs) in the northwest of Tai Lake Basin, China.

Poly- and perfluoroalkyl substances (PFASs) have attracted mounting attention due to their potential harmful effects and degradation-resistant property. This study continuously monitored the concentration of PFASs for four seasons in two years in the northwest of Tai Lake Basin. The occurrence, spatiotemporal distribution, seasonal and annual variation, and source apportionment of 13 PFASs were investigated in 60 surface water sampling sites and 33 emission sources. The average concentrations of the total PFASs were 205.6 ng L-1 and 171.9 ng L-1 in 2018 and 2019, respectively. This improvement could be mainly attributed to the local industrial restructuring. Furthermore, principal component analysis and heat map-hierarchical cluster analysis were employed to analyze distribution characteristics and the possible sources of PFASs pollution. It showed that perfluorooctane sulfonate (PFOA) mainly originated from the effluents of chemical plants, while the potential source of perfluorohexane sulfonate (PFHxS) included all the three types of emission sources. Besides, two indicators were adopted to evaluate the impact of non-point sources and the result showed the effect of runoff was obvious while the effect of atmospheric deposition was weak. A systematic mass balance calculation showed that the total riverine input flux from Wujin District to Tai Lake was 126.5 kg/a.